industry news
Subscribe Now

Gwangju Institute of Science and Technology Researchers Improve the Solubility of Redox Molecules for Enhanced Energy Storage Systems

Researchers introduce hydrotropic-supporting electrolyte to enhance the solubility of organic redox molecules for electrochemical capacitors
Redox-enhanced electrochemical capacitors (ECs) are a sustainable alternative to the dominant battery technologies that use metal ions and corrosive chemicals. However, obtaining organic redox-active electrolytes with sufficient solubility for use in redox-enhanced ECs is challenging. Now, researchers from Korea have introduced a hydrotropic-supporting electrolyte with tailor-made organic redox-active species for ECs, which results in increased solubility of the redox-active species without sacrificing electrochemical kinetics.
Dominant battery technologies using flammable, toxic, unsustainable, and expensive energy sources are a major contributor to climate change. Switching from fossil fuels to cleaner and environmentally friendly energy sources is thus crucial to curtail the impacts of climate change. This transition can be supported by improving the efficiency of energy storage systems for safer and stable operations, sustainability, high energy/ power density.
Research on this front has focused on molecular engineering approaches to the development of aqueous-based redox-enhanced electrochemical capacitors (redox ECs). Redox ECs are a type of advanced hybrid electric double-layer capacitors that use redox-active molecules at the electrode-electrolyte interface to increase the energy density. Owing to the use of organic redox-active electrolytes, they are known to provide a cost merit, use of earth-abundant elements, and structural tunability. However, a major challenge in their development is the lack of sufficient solubility of these species in aqueous systems, which results in a low energy density. Furthermore, previous attempts at improving their solubility have proven to be time-consuming and cost extensive.
Now, researchers from Korea have used hydrotropic-supporting electrolyte (HSE) as an approach to enhancing the solubility of the organic redox-active species. The study, led by Assistant Professor Seung Joon Yoo and Professor Sukwon Hong from Gwangju Institute of Science and Technology in Korea, was made available online on 20 April 2023 and was published in Volume 8, Issue 5 of the journal ACS Energy Letters on 12 May 2023.
The researchers used the process of hydrotropy, wherein a class of amphiphilic molecules are used. In this unique solubilization phenomenon, the volume of the hydrophobic component is relatively small compared to that of the surfactant, thus allowing an increase in the solubility of the sparingly soluble solute multifold. The researchers tested a range of quinones as a model species owing to their utility as a redox-active additive and an acceptable electrochemical stability.
The researchers found that using the HSE (p-toluene sulfonic acid (p-TsOH), 2-naphthalenesulfonic acid (2-NpOH), and anthraquinone-2-sulfonic acid (AQS)) improved the solubility of hydroquinone (HQ) without any chemical functionalization. Importantly, they demonstrated that an increase in the solubility is proportional to the concentration of the respective HSEs.
Moreover, they designed a biredox salt, 2-[N,N,N-tris(2-hydroxyethyl)] anthracenemethanaminum-9,10-dione bromide (AQM-Br), which could participate in Faradaic reactions at both the positive and negative electrodes, and tested it in the HSE system in a concentration-dependent manner. Dr. Yoo highlights, “The solubility of HQ in HSE was increased 7-fold, and a designer multifunctional dual-redox species (AQM-Br) was synthesized, the solubility of which was significantly enhanced from being barely soluble to >1 M by optimizing the HSE.
Furthermore, the researchers also attempted to understand the action of solubilization for both the HQ and AQM-Br electrolyte. Using the intermolecular nuclear Overhauser effect and dynamic light scattering analyses, they found that the hydrotrope solubilization for HQ/HSE was achieved through the co-solubilizer mechanism, whereas for AQM-Br/HSE, it was due to the formation of quasi-micelle nanostructures.
Explaining the potential implications of the study, Prof. Yoo concludes, “Our simple approach can be readily extended to a different class of redox species and find applicable to a wide variety of applications including redox flow batteries.”In addition, our study provides a guideline for the design of energy-dense redox-active electrolytes and an optimal selection of HSE and redox-active electrolyte pairs. 
Are redox ECs the future? It certainly looks like they’re here to stay!
Authors: Jinhwan Byeon1, Jinhyuck Ko2, Subin Lee2, Da Hye Kim2, Sung Won Kim2, Dowon Kim3, Wangsuk Oh4, Sukwon Hong1, and Seung Joon Yoo2
Title of original paper: Solubility-Enhancing Hydrotrope Electrolyte with Tailor-Made Organic Redox-Active Species for Redox-Enhanced Electrochemical Capacitors
Journal: ACS Energy Letters
1Department of Chemistry, Gwangju Institute of Science and Technology
2School of Materials Science and Engineering,Gwangju Institute of Science and Technology
3Department of Chemistry, Gwangju Institute of Science and Technology
4Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana−Champaign
*Corresponding author’s email:
About the Gwangju Institute of Science and Technology (GIST)
The Gwangju Institute of Science and Technology (GIST) is a research-oriented university situated in Gwangju, South Korea. Founded in 1993, GIST has become one of the most prestigious schools in South Korea. The university aims to create a strong research environment to spur advancements in science and technology and to promote collaboration between international and domestic research programs. With its motto of “A Proud Creator of Future Science and Technology,” GIST has consistently received one of the highest university rankings in Korea.

Leave a Reply

featured blogs
Jul 20, 2024
If you are looking for great technology-related reads, here are some offerings that I cannot recommend highly enough....

featured video

How NV5, NVIDIA, and Cadence Collaboration Optimizes Data Center Efficiency, Performance, and Reliability

Sponsored by Cadence Design Systems

Deploying data centers with AI high-density workloads and ensuring they are capable for anticipated power trends requires insight. Creating a digital twin using the Cadence Reality Digital Twin Platform helped plan the deployment of current workloads and future-proof the investment. Learn about the collaboration between NV5, NVIDIA, and Cadence to optimize data center efficiency, performance, and reliability. 

Click here for more information about Cadence Data Center Solutions

featured paper

Navigating design challenges: block/chip design-stage verification

Sponsored by Siemens Digital Industries Software

Explore the future of IC design with the Calibre Shift left initiative. In this paper, author David Abercrombie reveals how Siemens is changing the game for block/chip design-stage verification by moving Calibre verification and reliability analysis solutions further left in the design flow, including directly inside your P&R tool cockpit. Discover how you can reduce traditional long-loop verification iterations, saving time, improving accuracy, and dramatically boosting productivity.

Click here to read more

featured chalk talk

Industrial Drives and Pumps -- onsemi and Mouser Electronics
Sponsored by Mouser Electronics and onsemi
In this episode of Chalk Talk, Amelia Dalton and Bob Card and Hunter Freberg from onsemi discuss the benefits that variable frequency drive, semiconductor optimization, and power switch innovation can bring to industrial motor drive applications. They also examine how our choice of isolation solutions and power packages can make a big difference for these kinds of applications and how onsemi’s robust portfolio of intelligent power modules, current sensing solutions and gate drivers are a game changer when it comes to industrial motor drive applications.
Mar 25, 2024